Faculty Database - TSUTIMOTO Teruhisa

（Last updated : 2023-02-22 11:03:00）

TSUTIMOTO Teruhisa
Department Undergraduate School , School of Science and Technology

Position Professor

■ Books and Papers

1.	2023/01	Article	Synthesis of o-bis(3-indolyl)arenes under Brønsted acid catalysis: carbonyl compounds as sources of aryl groups Adv. Synth. Catal. in press (Collaboration)
2.	2021/02	Article	In(ONf)3-catalyzed 7-membered carbon-ring-forming annulation of heteroarylindoles with α,β-unsaturated carbonyl compounds Org. Chem. Front. 8,pp.2882-2892 (Collaboration)
3.	2020/11	Article	Stepwise Suzuki−Miyaura Cross‐Coupling of Triborylalkenes Derived from Alkynyl−B(dan)s: Regioselective and Flexible Synthesis of Tetrasubstituted Alkenes Adv. Synth. Catal. 363,pp.2427-2442 (Collaboration)
4.	2020/06	Article	Zinc/Indium Bimetallic Lewis Acid Relay Catalysis for Dehydrogenative Silylation/Hydrosilylation Reaction of Terminal Alkynes with Bis(hydrosilane)s Adv. Synth. Catal. 362,pp.4098-4108 (Collaboration)
5.	2019/10	Article	Direct Suzuki–Miyaura Coupling with Naphthalene-1,8-diaminato (dan)-Substituted Organoborons ACS Catal. 10,pp.346-351 (Collaboration)
6.	2019/08	Article	A Drastic Effect of TEMPO in Zinc‐Catalyzed Stannylation of Terminal Alkynes with Hydrostannanes via Dehydrogenation and Oxidative Dehydrogenation Adv. Synth. Catal. 361,pp.4314-4323 (Collaboration)
7.	2019/04	Article	Alkylation of Terminal Alkynes under Zinc Lewis Acid Catalysis and Its Mechanistic Studies Adv. Synth. Catal. 361,pp.2825-2831 (Collaboration)
8.	2019/01	Article	Alkynyl-B(dan)s in Various Palladium-Catalyzed Carbon-Carbon Bond-Forming Reactions Leading to Internal Alkynes, 1,4-Enynes, Ynones, and Multiply Substituted Alkenes Adv. Synth. Catal. 361,pp.1815-1834 (Collaboration)
9.	2018/04	Article	Indium-catalyzed annulation of o-acylanilines with alkoxyheteroarenes: synthesis of heteroaryl[b]quinolines and subsequent transformation to cryptolepine derivatives. Molecules 23,pp.838;1-18 (Collaboration)
10.	2018/01	Article	A heteroarylamine library: indium-catalyzed nucleophilic aromatic substitution of alkoxyheteroarenes with amines. Adv. Synth. Catal. 360,pp.1159-1181 (Collaboration)
11.	2017/08	Article	Zinc-catalyzed dehydrogenative silylation of indoles. Organometallics 36,pp.3234-3249 (Collaboration)
12.	2017/04	Article	Naked d-orbital in a centrochiral Ni(II) complex as a catalyst for asymmetric [3+2] cycloaddition. Nat. Commun. 8,pp.14875;1-10 (Collaboration)
13.	2017/03	Article	Indium-catalyzed regioselective β-alkylation of pyrroles with carbonyl compounds and hydrosilanes, and its application to constructing a quaternary carbon center with a β-pyrrolyl group. J. Org. Chem. 82,pp.5178-5197 (Collaboration)
14.	2016/08	Article	Indium-catalyzed formal N-arylation and N-alkylation of pyrroles with amines Adv. Synth. Catal. 358,pp.2895-2902 (Collaboration)
15.	2016/03	Article	Easy access to a library of alkylindoles: reductive alkylation of indoles with carbonyl compounds and hydrosilanes under indium catalysis Adv. Synth. Catal. 358,pp.1136-1149 (Collaboration)
16.	2016/01	Article	Carboxylative cyclization of propargylic amines with CO2 catalyzed by dendritic N-heterocyclic carbene-gold(I) complexes Tetrahedron 72,pp.1205-1212 (Collaboration)
17.	2014/11	Article	Alkynylboranes: a practical approach by zinc-catalyzed dehydrogenative coupling of terminal alkynes with 1,8-naphthalenediaminatoborane Adv. Synth. Catal. 357,pp.77-82 (Collaboration)
18.	2014/03	Article	Aqueous media carboxylative cyclization of propargylic amines with CO2 catalyzed by amphiphilic dendritic N-heterocyclic carbene-gold(I) complexes Tetrahedron Lett. 55,pp.3013-3016 (Collaboration)
19.	2014/03	Article	RE12 derivatives displaying Vaccinia H1-related phosphatase (VHR) inhibition in the presence of detergent and their anti-proliferative activity against HeLa cells Bioorg. Med. Chem. 22,pp.2771-2782 (Collaboration)
20.	2014/01	Article	Zinc-catalyzed direct cyanation of indoles and pyrroles: nitromethane as a source of a cyano group Adv. Synth. Catal. 356,pp.347-352 (Collaboration)
21.	2013/12	Article	Indium-catalyzed annulation of indoles with (2-ethynylaryl)methyl ethyl carbonates: synthesis and photoluminescent properties of aryl- and heteroaryl[b]carbazoles Chem. Lett. 42,pp.1170-1172 (Collaboration)
22.	2013/01	Article	Indium-catalyzed annulation of 3-aryl- and 3-heteroarylindoles with propargyl ethers: synthesis and photoluminescent properties of aryl- and heteroaryl[c]carbazoles Org. Biomol. Chem. 11,pp.1456-1459 (Collaboration)
23.	2012/12	Article	Homogeneous dihydroxylation of olefins catalyzed by OsO42- immobilized on a dendritic backbone with a tertiary nitrogen at its core position Chem. Pharm. Bull. 60,pp.1594-1598 (Collaboration)
24.	2012/10	Article	Dehydrogenative silylation of terminal alkynes with hydrosilanes under zinc-pyridine catalysis Adv. Synth. Catal. 354,pp.2959-2964 (Collaboration)
25.	2012/06	Article	Zinc-catalyzed dehydrogenative N-silylation of indoles with hydrosilanes Chem. Eur. J. 18,pp.9500-9504 (Collaboration)
26.	2011/05	Article	Catalytic Asymmetric α-chlorination of 3-acyl-oxazolidin-2-one with a trinary catalytic system Eur. J. Org. Chem. pp.3675-3678 (Collaboration)
27.	2011/04	Article	Magnetically recoverable osmium catalysts for dihydroxylation of olefins Tetrahedron Lett. 52,pp.3137-3140 (Collaboration)
28.	2011/03	Article	Selective synthesis of β-alkylpyrroles Chem. Eur. J. 17,pp.4064-4075 (Single)
29.	2011/01	Article	Reductive alkylation of indoles with alkynes and hydrosilanes under indium catalysis Org. Lett. 13,pp.912-915 (Collaboration)
30.	2011	Article	Development of new catalytic reactions based on activation of hydrocarbon functional groups by Lewis acids J. Synth. Org. Chem., Jpn. pp.889-903 (Single)
31.	2010/12	Article	Indium-catalyzed heteroaryl–heteroaryl bond formation through nucleophilic aromatic substitution Angew. Chem. Int. Ed. 50(6),pp.1375-1379 (Collaboration)
32.	2010/12	Article	Microwave-assisted organic functionalization of silica surfaces: effect of selectively heating silylating agents J. Organomet. Chem. 696(4),pp.825-828 (Collaboration)
33.	2010/10	Article	A recyclable dendritic osmium catalyst for homogeneous dihydroxylation of olefins Tetrahedron 66(44),pp.8536-8543 (Collaboration)
34.	2010/08	Article	Organic functionalization of the surface of silica with arylsilanes. A new method for synthesizing organic–inorganic hybrid materials J. Organomet. Chem. 695(23),pp.2540-2542 (Collaboration)
35.	2010/07	Article	Exclusive synthesis of β-alkylpyrroles under indium catalysis: carbonyl compounds as sources of alkyl groups Chem. Eur. J. 16(30),pp.8975-8979 (Collaboration)
36.	2010/03	Article	Development of innovative one-step synthesis of .beta.-alkylpyrroles Meiji Daigaku Kagaku Gijyutsu Kenkyusho Nenpo 50,pp.68-69 (Single)
37.	2009/12	Article	Homogeneous dihydroxylation of olefins catalyzed by a recyclable OsO42– core dendrimer Tetrahedron Lett. 51(5),pp.808-810 (Collaboration)
38.	2009/04	Article	Indium-catalyzed reductive alkylation of pyrroles with alkynes and hydrosilanes: selective synthesis of β-alkylpyrroles Org. Lett. 11(10),pp.2129-2132 (Collaboration)
39.	2009/04	Article	Synthesis of methanes having four different carbon substituents utilizing indium-catalyzed cleavage of carbon–pyrrolyl bonds Eur. J. Org. Chem. (15),pp.2437-2440 (Collaboration)
40.	2008/11	Article	Indium-catalyzed annulation of 2-aryl- and 2-heteroarylindoles with propargyl ethers: concise synthesis and photophysical properties of diverse aryl- and heteroaryl-annulated[a]carbazoles J. Am. Chem. Soc. 130(47),pp.15823-15835 (Collaboration)
41.	2008/07	Article	Lewis acid-catalyzed addition of pyrazoles to alkynes: selective synthesis of double and single addition products Eur. J. Org. Chem. (23),pp.4085-4040 (Collaboration)
42.	2008/05	Article	Direct coupling of N-H bond and H-C bond Organometallic News pp.82 (Single)
43.	2007/01	Article	Stereochemistry in Lewis acid-catalyzed silylation of alcohols, silanols, and methoxysilanes with optically active methyl(1-naphthyl)phenylsilane Silicon Chem. 3(5),pp.243-249 (Collaboration)
44.	2006/12	Article	Ruthenium-catalyzed addition of alkynes to alkynylstannanes with migration of the stannyl group Bull. Chem. Soc. Jpn. 79(12),pp.1963-1976 (Collaboration)
45.	2006/05	Article	Nickel-catalyzed addition of organoboronates to 1,2-dienes and the corresponding three- component reaction with an alkyne Wiley-VCH Adv. Synth. Catal. 348,pp.837-340 (Collaboration)
46.	2005/10	Article	A simple catalust system for the palladium-catalyzed coupling of aryl halides with terminal alkynes 'Elsevier, Tetrahedron' 61,pp.pp97878-9885 (Collaboration)
47.	2005/07	Article	Indium-catalysed synthesis of aryl- and heteroaryl-annulated carbazoles: systematic inveatigation of their emission properties IUPAC OMCO-13 Abstracts　Geneva (Collaboration)
48.	2005/02	Article	'Synthesis of multisubstituted 1,3-butadienes using the ruthenium-catalysed double addition of trimethyl-silyldiazomethane to alkynylboronates' 'RSC Publishing, Org. Biomol. Chem.' 3,pp.pp1263-1268 (Collaboration)
49.	2005/02	Article	Easy access to aryl- and heteroary-annulated [a]carbazoles by the indium-catalyzed reaction of 2-arylindoles with propargyl ethers Wiley-VCH Angew.Chem.Int.Ed. 44,pp.pp1336-1340 (Collaboration)
50.	2005/01	Article	Alkynes as activators in the nickel-catalysed addition of organoboronates aldehydes 'RSC Publishing, Chem. Commun.' pp.pp1459-1461 (Collaboration)
51.	2004/11	Article	'Synthetic strategy for functionalized polyacene atructure using nickel-catalyzed alkynylstannylation of 1,2-dienes' Trans. MRS-J. 29,pp.pp93-96 (Collaboration)
52.	2004/10	Article	A ρ-phosphinophenolate ligand for the palladium-catalysed arylation of alkenes 'RSC Publishing, Chem. Commun.' pp.pp2752-2753 (Collaboration)
53.	2004/10	Article	Ruthenium-catalyzed hydrogennnation of alkylstannanes with migration of the stannyl group 'ACS Publications, J. Am. Chem. Soc.' 126,pp.pp13614-13615 (Collaboration)
54.	2004/08	Article	'Nickel-catalyzed acylstannylation and alkynyatannylation of 1,2-dienes' 'Elsevier, J. Organomet. Chem.' 689,pp.pp3701-3721 (Collaboration)
55.	2004/08	Article	Zirconium triflate catalyzed direct coupling reaction of lactams with heterocyclic arenes under atmospheric oxygen Wiley-VCH Angew.Chem.Int.Ed. 43,pp.pp4231-4233 (Collaboration)
56.	2004/06	Article	'Nickel-catalyzed tandem carbonstannylation of alkynes and 1,2-dienes with alkynylstannanes' Wiley-VCH Angew.Chem.Int.Ed. 43,pp.pp3448-3451 (Collaboration)
57.	2003/09	Article	Indium triflate-catalysed double addition of heterocyclic arenesvto alkynes 'RSC Publishing, Chem. Commun.' pp.pp2454-2455 (Collaboration)
58.	2003/03	Article	Palladium-catalysed dimerization of vinylarenes using indium triflate as an effective co-catalyst The 3nd JAIST-POSTEC joint symposium Abstracts Pohang pp.p27 (Collaboration)
59.	2003/03	Article	Palladium-catalysed dimerization of vinylarenes using indium triflate as an effective co-catalyst 'RSC Publishing, Chem. Commun.' pp.pp852-853 (Collaboration)
60.	2002/09	Article	'Nickel-catalysed addition of organoboronates to 1,3-dienes' 'RSC Publishing, Chem. Commun.' pp.pp2210-2212 (Collaboration)
61.	2002/08	Article	'Synthesis of polycyclic compounds utilizing the nickel-catalysed alkynylstannylation of 1,2-dienes' 'RSC Publishing, Chem. Commun.' pp.pp1962-1963 (Collaboration)
62.	2002/03	Article	Metal triflate-catalyzed addition of arenes to alkynes The 2nd JAIST-POSTEC joint symposium Abstracts pp.p30 (Collaboration)
63.	2001/12	Article	Nickel-catalysed hydroarylation of alkynes using arylboron compounds: selective synthesis of multisubstituted arylalkenes and aryldienes 'RSC Publishing, Chem. Commun.' pp.pp2688-2689 (Collaboration)
64.	2001/09	Article	'Transition metal-catalysed acylation of α,β-unsaturated carbonyl compounds with acylstannanes' 'RSC Publishing, Chem. Commun.' pp.pp1926-1927 (Collaboration)
65.	2001/07	Article	Dimerization of alkenes catalyzes by a palladium-metal triflate system PostOMCO-11 Abstacts pp.p168 (Collaboration)
66.	2000/12	Article	Brφnsted acid-catalyzed hydration of alkynes: a convenient route to diverse carbonyl compounds Thieme Synlett pp.pp1777-1778 (Collaboration)
67.	2000/08	Article	Friedel-Crafts alkenylation of arenes using alkynes catalused by metal trifluoromethanesufinates 'RSC Publishing, Chem. Commun.' pp.pp1573-1574 (Collaboration)
68.	2000/07	Article	Friedel-Crafts alkenylation of arenes using alkynes catalused by metal trifluoromethanesufinates IKCOC-8 Absracts pp.p200 (Collaboration)
69.	1999/03	Article	Synthtic applications of ortho esters IUPAC Pure Appl. Chem. 71,pp.pp415-422 (Collaboration)
70.	1997/09	Article	Scandium(III) triflate-catalyzed Friedel-Crafts alkylation reactions 'ACS Publications, J. Org. Chem.' 62,pp.pp6997-7005 (Collaboration)
71.	1997/01	Article	Superacid-catalyzed reductive Friedel-Crafts reaction of arenes using arenecarbaldehyde acetals 'ACS Publications, J. Org. Chem.' 62,pp.pp151-156 (Collaboration)
72.	1996/10	Article	'Scandium(III) trifluoromethanesulfonate-catalysed reductive Friedel-Crafts benzylation of aromatic compounds using arenecarbaldehydes and propane-1,3-diol' 'RSC Publishing, Chem. Commun.' pp.pp2345-2346 (Collaboration)
73.	1996/07	Article	Samarium(II) triflate as a new reagent for the Grignard-type carbonyl addition reaction 'ACS Publications, J. Org. Chem.' 61,pp.pp5400-5405 (Collaboration)
74.	1996/06	Article	Scandium(III) triflate catalyzed Friedel-Crafts alkylation with benzyl and alltl alcohols Thieme Synlett pp.pp557-559 (Collaboration)
75.	1996/02	Article	Alkylation-annulation of halo esters with organometallic reagent/SmI2 cupile leading to cycloalkanols: afacile cyclopropanol synthesis from a halo ester Elsevier Tetrahedron Lett. 52,pp.pp1953-1960 (Collaboration)
76.	1995/10	Article	Direct synthesis of chiral acetals from carbonyl compounds and chiral diols: sequential one-pot asymmetric silylcyanation reaction catalyzed by scandium(III) triflate Thieme Synlett pp.pp1077-1078 (Collaboration)
77.	1995/08	Article	A facile conversion of substituted cyclobutanones to cyclopentanones by CH2I2/SmI2 system Elsevier Tetrahedron Lett. 36,pp.pp5937-5938 (Collaboration)
78.	1995/08	Article	A facile one-pot synthesis of chiral acetals and subsequent C-C bond forming reactions catalyzed by Ln(OTf)3 IUPAC OMCO-8 Abstracts　Santa Barbara pp.p205 (Collaboration)
79.	1994/08	Article	Preparation of samarium(II) triflate and it mediated Grignard-type reaction. In situ formation and reaction of new organosamarium reagents Chem.Lett. pp.pp1981-1984 (Collaboration)
80.	1994/08	Article	Ytterbium trifluoromethafonate mediated cross-aldol reaction between ketones and aldehydes Bull.Chem.Soc.Jpn. 67,pp.pp2227-2232 (Collaboration)
81.	1993/10	Article	Samarium(II) Diiodide induced intramolecular coupling reaction of haloacetals leading to the synthesis of γ-lactones 'Thieme,Synett' pp.pp803-804 (Collaboration)
82.	1993/09	Article	Samarium(II) diiodide induced intramolecular coupling reaction of haloacetals leading to synthesis of γ-lactones IUPAC OMCO-7 Abstracts pp.p107 (Collaboration)
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■ Conference Presentations

2011/09/06

Exclusive synthesis of β-alkylpyrroles under indium catalysis (14th Asian Chemical Congress (14ACC))

■ Academic Qualifications

1.	～1997/03	〔Doctorial Course〕, Tokyo Institute of Technology, Completed, Ph. D
2.	～1994/03	〔Master Course〕, Graduate School, Division of Science and Engineering, Chuo University, Completed,
3.	～1992/03	Faculty of Science and Engineering, Chuo University, Graduated,

■ Current Specialized Field

Bioorganic chemistry