オオタケ　ヨシノブ   Otake Yoshinobu   大竹　芳信    所属   明治大学  理工学部    職種   専任准教授
言語種別	英語
発行・発表の年月	2010/11
形態種別	学術雑誌
標題	Control of mesoporous and crystalline structures in turbostratic carbon derived from Fe- or Ni-doped phenolic resin
執筆形態	共著(筆頭者以外)
掲載誌名	Journal of Materials Science
巻・号・頁	46,pp.2194-2200
著者・共著者	Katsuya Inomata, Yoshinobu Otake
概要	A technique to control the mesoporous structure and crystallites present in turbostratic carbon (Ts-carbon) derived from Fe- and Ni-doped phenolic resin is described. To eliminate the effect of heat treatment temperature, all of the Fe- and Ni-doped phenolic resins are carbonized at a fixed temperature of 1000 °C. The catalyst content in the obtained Ts-carbon varies from 0.001 to 5 mmol/g. Mesopores and turbostratic crystallites are formed in the Ts-carbon samples, and these increase in size as the catalyst content and its particle size increases. The turbostratic crystallites assemble to form carbon aggregates with a cup- stacked, thin tube-like, or coil-like structure. The mesopore surface area increases proportionally with the amount of turbostratic crystallites rather than the type of carbon aggre- gate. It is proposed that the mesopore is surrounded by tur- bostratic crystallites. Altering the size of the turbostratic crystallites in Ts-carbon has revealed an effective method for controlling the size and volume of its mesopores.
DOI	10.1007/s10853-010-5057-4