オガワ トシユキ   OGAWA Toshiyuki
  小川 知之
   所属   明治大学  総合数理学部
   職種   専任教授
言語種別 日本語
発行・発表の年月 2008/01
形態種別 書籍掲載論文
査読 査読あり
標題 Selection principle for various modes of spatially nonuniform electrochemical oscillations
執筆形態 共著(筆頭者以外)
掲載誌名 Journal of Chemical Physics
掲載区分国外
巻・号・頁 128
著者・共著者 Satoshi Fukushima, Shuji Nakanishi, Shuji Nakanishi, Yoshihiro Nakato, Toshiyuki Ogawa
概要 The pattern selection principle for various modes of spatially nonuniform oscillation was investigated by taking a current oscillation of negative differential resistance type, appearing in H2 O2 reduction on platinum (Pt) ring electrodes, as a model system. In experiments, various modes of spatiotemporal oscillation, such as a spatially uniform oscillation, standing wave oscillation, and rotating wave oscillation, appeared depending on the applied potential and the distance between the Pt-ring electrode and the reference electrode. A simple mathematical model for the spatiotemporal patterns at the electrode surface was proposed. Numerical calculations and nonlinear bifurcation analysis based on the proposed model reproduced all the essential features of the experimental results and clarified the pattern selection principle. ? 2008 American Institute of Physics.
DOI 10.1063/1.2799994
ISSN 00219606
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