イシトビ ヒロカズ   ISHITOBI HIROKAZU
  石飛 宏和
   所属   明治大学  理工学部
   職種   専任准教授
言語種別 英語
発行・発表の年月 2016
形態種別 学術雑誌
査読 査読あり
標題 Effect of the impurities in bioethanol on current density of a direct ethanol fuel cell
執筆形態 共著(筆頭者)
掲載誌名 Nihon Enerugi Gakkaishi/Journal of the Japan Institute of Energy
掲載区分国外
出版社・発行元 Japan Institute of Energy
巻・号・頁 95(10),pp.909-914
著者・共著者 Hirokazu Ishitobi,Daiki Naito,Yurina Ino,Masaya Yajima,Nobuyoshi Nakagawa
概要 The degradation of current density by impurities in bioethanol from lignocellulosic biomass for use in a direct ethanol fuel cell was evaluated. The degradation experiment of using a single cell was conducted by adding nine impurities, i.e., methanol, acetaldehyde, acetic acid, 1-propanol, allyl alcohol, ethyl acetate, 3-methyl-1-butanol, acetal (acetaldehyde diethyl acetal), and benzaldehyde, to a 2 M ethanol aqueous solution. The current density of the single cell was degraded by the quasi bioethanol including the nine impurities. To clarify the principal poisoning impurity, we performed the cell measurement by only adding each single impurity. As a result, allyl alcohol turned out to be the main catalyst poison under the estimated condition. The negative effects by the other impurities were almost negligible.
DOI 10.3775/jie.95.909
ISSN 0916-8753