タハラ　カズクニ   TAHARA KAZUKUNI   田原　一邦    所属   明治大学  理工学部    職種   専任教授
言語種別	英語
発行・発表の年月	2010/12
形態種別	学術雑誌
標題	Supramolecular surface-confined architectures created by self-assembly of triangular phenylene-ethynylene macrocycles via van der Waals interaction
執筆形態	共著(筆頭者)
掲載誌名	Chemical Communications
掲載区分	国外
巻・号・頁	46(45),pp.8507-8525
担当区分	筆頭著者
国際共著	国際共著
著者・共著者	Kazukuni Tahara,Shengbin Lei,Jinne Adisoejoso,Steven De Feyter,Yoshito Tobe
概要	At the liquid/graphite interface triangular and rhombic phenylene-ethynylene macrocycles substituted by alkyl chains self-assemble to form porous two-dimensional (2D) molecular networks of honeycomb and Kagomé types, respectively, or close-packed non-porous structures via alkyl chain interdigitation as the directional intermolecular linkages. Factors that affect the formation of the 2D molecular networks, such as alkyl chain length, solvent, solute concentration, and co-adsorption of guest molecules, were elucidated through a systematic study. For the porous networks, various molecules and molecular clusters were adsorbed in the pores reflecting the size and shape complementarity, exploring a new field of 2D host-guest chemistry. © 2010 The Royal Society of Chemistry.
DOI	10.1039/c0cc02780d
ISSN	1359-7345