イワセ アキヒデ   IWASE AKIHIDE
  岩瀬 顕秀
   所属   明治大学  理工学部
   職種   専任教授
言語種別 英語
発行・発表の年月 2017/06
形態種別 学術雑誌
査読 査読あり
標題 Capturing local structure modulations of photoexcited BiVO4 by ultrafast transient XAFS.
執筆形態 共著(筆頭者以外)
掲載誌名 Chemical communications
掲載区分国外
巻・号・頁 53,pp.7314-7317
著者・共著者 Uemura Yohei, Kido Daiki, Koide Akihiro, Wakisaka Yuki, Niwa Yasuhiro, Nozawa Shunsuke, Ichiyanagi Kohei, Fukaya Ryo, Adachi Shin-Ichi, Katayama Tetsuo, Togashi Tadashi, Owada Shigeki, Yabashi Makina, Hatada Keisuke, Iwase Akihide, Kudo Akihiko, Takakusagi Satoru, Yokoyama Toshihiko, Asakura Kiyotaka
概要 Ultrafast excitation of photocatalytically active BiVO4 was characterized by femto- and picosecond transient X-ray absorption fine structure spectroscopy. An initial photoexcited state (≪500 fs) changed to a metastable state accompanied by a structural change with a time constant of ∼14 ps. The structural change might stabilize holes on oxygen atoms since the interaction between Bi and O increases.
DOI 10.1039/c7cc02201h
ISSN 1364-548X
PMID 28480915