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IWASE AKIHIDE
Department Undergraduate School , School of Science and Technology Position Professor |
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| Language | English |
| Publication Date | 2017/06 |
| Type | Academic Journal |
| Peer Review | Peer reviewed |
| Title | Capturing local structure modulations of photoexcited BiVO4 by ultrafast transient XAFS. |
| Contribution Type | Co-authored (other than first author) |
| Journal | Chemical communications |
| Journal Type | Another Country |
| Volume, Issue, Page | 53,pp.7314-7317 |
| Author and coauthor | Uemura Yohei, Kido Daiki, Koide Akihiro, Wakisaka Yuki, Niwa Yasuhiro, Nozawa Shunsuke, Ichiyanagi Kohei, Fukaya Ryo, Adachi Shin-Ichi, Katayama Tetsuo, Togashi Tadashi, Owada Shigeki, Yabashi Makina, Hatada Keisuke, Iwase Akihide, Kudo Akihiko, Takakusagi Satoru, Yokoyama Toshihiko, Asakura Kiyotaka |
| Details | Ultrafast excitation of photocatalytically active BiVO4 was characterized by femto- and picosecond transient X-ray absorption fine structure spectroscopy. An initial photoexcited state (≪500 fs) changed to a metastable state accompanied by a structural change with a time constant of ∼14 ps. The structural change might stabilize holes on oxygen atoms since the interaction between Bi and O increases. |
| DOI | 10.1039/c7cc02201h |
| ISSN | 1364-548X |
| PMID | 28480915 |