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TAHARA KAZUKUNI
Department Undergraduate School , School of Science and Technology Position Professor |
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| Language | English |
| Publication Date | 2010/12 |
| Type | Academic Journal |
| Title | Supramolecular surface-confined architectures created by self-assembly of triangular phenylene-ethynylene macrocycles via van der Waals interaction |
| Contribution Type | Co-authored (first author) |
| Journal | Chemical Communications |
| Journal Type | Another Country |
| Volume, Issue, Page | 46(45),pp.8507-8525 |
| Authorship | Lead author |
| International coauthorship | International coauthorship |
| Author and coauthor | Kazukuni Tahara,Shengbin Lei,Jinne Adisoejoso,Steven De Feyter,Yoshito Tobe |
| Details | At the liquid/graphite interface triangular and rhombic phenylene-ethynylene macrocycles substituted by alkyl chains self-assemble to form porous two-dimensional (2D) molecular networks of honeycomb and Kagomé types, respectively, or close-packed non-porous structures via alkyl chain interdigitation as the directional intermolecular linkages. Factors that affect the formation of the 2D molecular networks, such as alkyl chain length, solvent, solute concentration, and co-adsorption of guest molecules, were elucidated through a systematic study. For the porous networks, various molecules and molecular clusters were adsorbed in the pores reflecting the size and shape complementarity, exploring a new field of 2D host-guest chemistry. © 2010 The Royal Society of Chemistry. |
| DOI | 10.1039/c0cc02780d |
| ISSN | 1359-7345 |